C3H7 + H2O2 -> C3H8 + HO2

k = 3.78E+02 T^2.72 exp(- 1500 cal/mol /RT) cm3/mol s

SOURCE:: 3-parameter fit to Tsang (1988) expression for reverse rate constant.

COMMENTS:

REFERENCES:: Tsang, W. (1988) J. Phys. Chem. Ref. Data 17, 887.

______________________________________________________________

  Temp       DS          DH        kf        kr        Keq
   (K)   (cal/mol K)  (kcal/mol)   ----- (mol,cm3,s)  -----    
______________________________________________________________

   298      -5.9       -13.3    1.62E+08  5.98E-01  2.70E+08
   300      -5.9       -13.3    1.67E+08  7.10E-01  2.35E+08
   400      -6.3       -13.4    6.85E+08  7.76E+02  8.82E+05
   500      -6.5       -13.5    1.83E+09  6.12E+04  3.00E+04
  1000      -6.9       -13.7    2.57E+10  8.18E+08  3.14E+01
  1500      -6.8       -13.6    9.95E+10  3.15E+10  3.16E+00
  2000      -6.6       -13.2    2.47E+11  2.41E+11  1.02E+00
  2500      -6.4       -12.7    4.88E+11  9.18E+11  5.32E-01
  3000      -6.1       -12.2    8.43E+11  2.41E+12  3.50E-01
______________________________________________________________

[ Rate coefficient format | Chemkin file | Thermo data | Main menu ]