From the results of a 2-channel variational RRKM calculation of Wagner and Harding (1992). (A. F. Wagner, private communication, 1996) See figure below for a comparison to experimental data. The related CH3 decomposition reactions are 50 and 289.
REFERENCES:
______________________________________________________________________ Temp delta-S delta-H kf kr Keq (K) (cal/mol K) (kcal/mol) ----(mol,cm3,s)----- ______________________________________________________________________ 300 -1.1 3.1 5.86E+11 1.86E+14 3.15E-03 500 -1.2 3.1 4.72E+12 1.91E+14 2.47E-02 1000 -1.0 3.3 2.26E+13 1.90E+14 1.19E-01 1500 -.7 3.6 3.80E+13 1.81E+14 2.11E-01 2000 -.6 3.8 4.94E+13 1.72E+14 2.87E-01 2500 -.6 3.8 5.78E+13 1.66E+14 3.48E-01 3000 -.7 3.6 6.42E+13 1.63E+14 3.94E-01 _____________________________________________________________________
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