CH2(S) + H2O -> H2 + CH2O

SOURCE:

The parameters represent the results of a 5-channel RRKM calculation on the CH3OH system.

COMMENTS:

This reaction channel was added to the mechanism in version 3.0. The likely product is HCOH which rapidly isomerizes to CH2O.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300        -6.9       -70.9    1.36E+12    0.00E+00    
     500        -6.9       -70.9    8.26E+11    0.00E+00    
    1000        -6.2       -70.4    6.14E+11    0.00E+00    
    1500        -5.6       -69.6    5.81E+11    0.00E+00    
    2000        -5.1       -68.9    5.77E+11    0.00E+00    
    2500        -4.9       -68.3    5.82E+11    0.00E+00    
    3000        -4.7       -67.7    5.90E+11    0.00E+00    
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