CH2(S) + O2 -> CO + H2O

k = 1.20E+13 cm3/mol s

SOURCE:
The rate coefficient of Langford et al. (1983) using the branching ratio suggested by Shaub et al. (1981).

COMMENTS:
Served as an optimization variable for GRI-Mech 3.0 and was not changed.
REFERENCES:
Langford et al. (1983)
Langford, A.O., Petek, H., and Moore, C.B. (1983) J. Chem. Phys. 78, 6650.
Shaub et al. (1981)
Shaub, W.M., Hsu, D.S.Y., Burks, T.L., and Lin, M.C. (1981) 18th Symposium (International) on Combustion, p. 811. 
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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----    
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     300        -1.9      -187.0    1.20E+13    1.96-123    6.11+135
     500        -2.0      -187.0    1.20E+13    6.00E-69    2.00E+81
    1000        -2.7      -187.5    1.20E+13    4.84E-28    2.48E+40
    1500        -3.1      -188.0    1.20E+13    2.29E-14    5.24E+26
    2000        -3.3      -188.4    1.20E+13    1.64E-07    7.31E+19
    2500        -3.4      -188.7    1.20E+13    2.16E-03    5.55E+15
    3000        -3.5      -188.9    1.20E+13    1.22E+00    9.87E+12
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