CH3 + C3H7 -> 2C2H5

SOURCE:

Sum of rate coefficients for all channels from Tsang 1988, who reports the products to be butane and propylene.

COMMENTS:

REFERENCES:

Arthur, N.L.; Anastasi, C. (1983) Bull. Soc. Chim. Belg. 92, 647.

Anastasi, C.; Arthur, N.L. (1987) J. Chem. Soc. Faraday Trans. 2: 83, 277.

Konar, R.S.; Marshall, R.M.; Purnell, J.H. (1968) Trans. Faraday Soc. 64, 405-413.

Tsang, W. (1988) J. Phys. Chem. Ref. Data 17, 887.

Tsang, W. (1989) Combust. Flame 78, 71-86.

______________________________________________________________

  Temp       DS          DH        kf        kr        Keq
   (K)   (cal/mol K)  (kcal/mol)   ----- (mol,cm3,s)  -----    
______________________________________________________________

   298       2.6        -2.4    3.12E+12  1.48E+10  2.11E+02
   300       2.6        -2.4    3.11E+12  1.51E+10  2.06E+02
   400       1.9        -2.6    2.84E+12  3.94E+10  7.19E+01
   500       1.4        -2.8    2.64E+12  7.30E+10  3.62E+01
  1000       0.5        -3.5    2.12E+12  2.83E+11  7.48E+00
  1500       0.4        -3.6    1.86E+12  4.52E+11  4.12E+00
  2000       0.4        -3.7    1.70E+12  5.60E+11  3.03E+00
  2500       0.4        -3.7    1.58E+12  6.27E+11  2.52E+00
  3000       0.3        -3.7    1.49E+12  6.70E+11  2.22E+00
______________________________________________________________