H + C3H8 -> C3H7 + H2

SOURCE:

Tsang, W. (1988) J. Phys. Chem. Ref. Data 17, 887.

COMMENTS:

Served as an optimization variable for GRI-Mech 3.0; the value was not changed.

REFERENCES:

Baker, R.R.; Baldwin, R.R.; Walker, R.W. (1970) Trans. Faraday Soc. 66, 2812.

Baldwin, R. F.; Walker, R. W. (1979) J. Chem. Soc. Faraday Trans. 1: 75, 140.

Dombi, A.; Huhn, P. (1986) Int. J. Chem. Kinet. 18, 241.

Dombi, A.; Huhn, P. (1986) Int. J. Chem. Kinet. 18, 227.

Dombi, A.; Huhn, P. (1985) Mag. Kem. Foly. 91, 22-27.

Dombi, A.; Huhn, P. (1985) Mag. Kem. Foly. 91, 27-31.

Hidaka, Y.; Oki, T.; Kawano, H. (1989) Int. J. Chem. Kinet. 21, 689.

Marshall, R.M.; Purnell, H.; Sheppard, A. (1984) J. Chem. Soc. Faraday Trans. 1: 80, 2999.

Tsang, W. (1988) J. Phys. Chem. Ref. Data 17, 887.

______________________________________________________________

  Temp       DS          DH        kf        kr        Keq
   (K)   (cal/mol K)  (kcal/mol)   ----- (mol,cm3,s)  -----    
______________________________________________________________

   298       8.4        -3.3    2.84E+07  1.67E+03  1.70E+04
   300       8.4        -3.3    3.10E+07  1.88E+03  1.65E+04
   400       8.8        -3.1    1.09E+09  2.54E+05  4.30E+03
   500       9.0        -3.1    1.05E+10  5.34E+06  1.97E+03
  1000       8.7        -3.3    1.84E+12  4.39E+09  4.19E+02
  1500       8.0        -4.1    1.60E+13  7.05E+10  2.27E+02
  2000       7.5        -5.1    5.85E+13  3.79E+11  1.54E+02
  2500       7.0        -6.1    1.45E+14  1.24E+12  1.17E+02
  3000       6.7        -7.0    2.89E+14  3.08E+12  9.38E+01
______________________________________________________________