H + CH3CHO -> CH3 + H2 + CO

SOURCE:

Baulch, D.L., Cobos, C.J., Cox, R.A., Esser, C., Frank, P., Just, Th., Kerr, J.A., Pilling, M.J., Troe, J., Walker, R.W., and Warnatz, J. (1992) J. Phys. Chem. Ref. Data 21, 411.

COMMENTS:

Rapid decomposition is assumed for the initial CH3CO product. A 50% branch goes to reaction 299 H+ CH3CHO => H2 + CH2CHO.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300        34.3        -3.7    2.71E+10    0.00E+00    
     500        36.1        -3.0    2.46E+11    0.00E+00    
    1000        35.6        -3.5    1.85E+12    0.00E+00    
    1500        34.3        -5.1    4.42E+12    0.00E+00    
    2000        33.3        -6.9    7.55E+12    0.00E+00    
    2500        32.4        -8.9    1.10E+13    0.00E+00    
    3000        31.7       -10.8    1.48E+13    0.00E+00         
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