H + CH3O (+M) -> CH3OH (+M)

k_o = 4.66E+41 T^(-7.44) exp(-14080 cal/mol /RT) cm^6/mol^2 s

k_inf = 2.43E+12 T^(0.515) exp(-50 cal/mol /RT) cm3/mol s

F_cent = (1-0.70) exp(-T/100) + 0.70 exp(-T/90000) + exp(-10000/T)

Third-body efficiencies:
N2 1.0
H2 Enhanced by 2.0
H2O Enhanced by 6.0
CH4 Enhanced by 2.0
CO Enhanced by 1.5
CO2 Enhanced by 2.0
C2H6 Enhanced by 3.0
SOURCE:
The parameters represent the results of a 5-channel RRKM calculation on the CH3OH system.
COMMENTS:
The pressure broadening is expressed in the Troe form. 

                        PRESSURE = 0.1 atm N2  
______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq     
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   (cm3/mol)  
______________________________________________________________________
                                                                    
     300       -24.7      -104.0    3.82E+07    6.47E-68    5.90E+74
     500       -26.5      -104.7    6.39E+09    1.63E-35    3.93E+44
    1000       -28.3      -106.0    2.18E+10    2.79E-12    7.80E+21
    1500       -29.0      -106.8    7.61E+09    3.68E-05    2.07E+14
    2000       -29.3      -107.4    2.20E+09    6.36E-02    3.46E+10
    2500       -29.5      -107.9    6.83E+08    3.56E+00    1.92E+08
    3000       -29.7      -108.2    2.36E+08    3.84E+01    6.15E+06
______________________________________________________________________


                        PRESSURE = 1 atm N2    
______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq     
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   (cm3/mol)  
______________________________________________________________________
                                                                      
     300       -24.7      -104.0    3.80E+08    6.44E-67    5.90E+74
     500       -26.5      -104.7    6.29E+10    1.60E-34    3.93E+44
    1000       -28.3      -106.0    2.14E+11    2.74E-11    7.80E+21
    1500       -29.0      -106.8    7.50E+10    3.62E-04    2.07E+14
    2000       -29.3      -107.4    2.18E+10    6.30E-01    3.46E+10
    2500       -29.5      -107.9    6.78E+09    3.53E+01    1.92E+08
    3000       -29.7      -108.2    2.35E+09    3.82E+02    6.15E+06
______________________________________________________________________


                        PRESSURE = 10 atm N2   
______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq     
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   (cm3/mol)  
______________________________________________________________________
                                                                      
     300       -24.7      -104.0    3.77E+09    6.39E-66    5.90E+74
     500       -26.5      -104.7    6.04E+11    1.54E-33    3.93E+44
    1000       -28.3      -106.0    2.00E+12    2.56E-10    7.80E+21
    1500       -29.0      -106.8    7.25E+11    3.50E-03    2.07E+14
    2000       -29.3      -107.4    2.14E+11    6.18E+00    3.46E+10
    2500       -29.5      -107.9    6.70E+10    3.49E+02    1.92E+08
    3000       -29.7      -108.2    2.33E+10    3.79E+03    6.15E+06
______________________________________________________________________

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