H + CH3O -> CH2(S) + H2O
k = 2.62E+14 T^(-.23) exp(-1070 cal/mol /RT) cm^3/mol
s
- SOURCE:
- The parameters represent the results of a 5-channel RRKM calculation
on the CH3OH system.
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Temp delta-S delta-H kf kr Keq
(K) (cal/mol K) (kcal/mol) ----(mol,cm3,s)-----
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300 8.3 -11.0 1.17E+13 1.58E+03 7.42E+09
500 8.8 -10.9 2.13E+13 4.44E+06 4.81E+06
1000 7.5 -11.9 3.12E+13 1.79E+09 1.74E+04
1500 6.2 -13.5 3.40E+13 1.63E+10 2.09E+03
2000 5.2 -15.2 3.48E+13 5.51E+10 6.32E+02
2500 4.5 -16.7 3.49E+13 1.23E+11 2.84E+02
3000 4.0 -18.2 3.47E+13 2.20E+11 1.58E+02
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