H + HO2 -> O2 + H2


k = 4.48E+13 exp(-1068 cal/mol /RT) cm3/mol s


SOURCE:
A least-squares fit to the data from Warnatz (1984), Sridharan et al. (1982), and Keyser (1986).

REFERENCES:
Sridharan et al. (1982)
Sridharan, W.C., Qiu, L.X. and Kaufman, F. (1982) J. Phys. Chem. 86, 4569.
Keyser (1986)
Keyser, L.F. (1986) J. Phys. Chem. 90, 2994.
Warnatz (1984)
Warnatz, J. (1984) in Combustion Chemistry, W.C. Gardiner, Ed., Springer-Verlag, Chap. 5.
COMMENTS:
Served as an optimization variable for GRI-Mech 3.0 and was increased by 1.6.

The GRI-Mech 1.2 value was increased by a factor of 1.6 for version 3.0


______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
______________________________________________________________________

     300        -1.9       -55.1    7.47E+12    1.41E-27    5.30E+39
     500        -1.7       -55.0    1.53E+13    3.20E-11    4.77E+23
    1000        -2.0       -55.3    2.62E+13    6.05E+01    4.33E+11
    1500        -2.4       -55.7    3.14E+13    7.95E+05    3.94E+07
    2000        -2.7       -56.3    3.42E+13    9.50E+07    3.60E+05
    2500        -2.9       -56.8    3.62E+13    1.73E+09    2.10E+04
    3000        -3.1       -57.3    3.74E+13    1.21E+10    3.09E+03
______________________________________________________________________

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