H + HO2 -> OH + OH


k = 8.4E+13 exp(-635 cal/mol /RT) cm3/mol s


SOURCE:
A least-squares fit to the data from Warnatz (1984), Sridharan et al. (1982), and Keyser (1986).

REFERENCES:
Sridharan et al. (1982)
Sridharan, W.C., Qiu, L.X. and Kaufman, F. (1982) J. Phys. Chem. 86, 4569.
Keyser (1986)
Keyser, L.F. (1986) J. Phys. Chem. 90, 2994.
Warnatz (1984)
Warnatz, J. (1984) in Combustion Chemistry, W.C. Gardiner, Ed., Springer-Verlag, Chap. 5.
COMMENTS:
Served as an optimization variable for GRI-Mech 3.0 and was multiplied by 0.62 in the optimization.

The GRI-Mech 1.2 value was multiplied by a factor of 0.62 for version 3.0


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    Temp         DS          DH        kf         kr         Keq
     (K)     (cal/mol K)  (kcal/mol)    ----- (mol,cm3,s)  -----    
______________________________________________________________________

     300         5.7       -36.3    2.90E+13    6.11E-15    4.74E+27
     500         5.8       -36.2    4.43E+13    3.41E-04    1.30E+17
    1000         5.0       -36.8    6.10E+13    4.28E+04    1.43E+09
    1500         4.4       -37.7    6.79E+13    2.44E+07    2.78E+06
    2000         3.9       -38.5    7.16E+13    6.27E+08    1.14E+05
    2500         3.5       -39.4    7.39E+13    4.59E+09    1.61E+04
    3000         3.2       -40.2    7.55E+13    1.78E+10    4.24E+03
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