HCO + H2O -> H + CO + H2O

SOURCE:

Tsang, W., and Hampson, R.F. (1986) J. Phys. Chem. Ref. Data 15, 1087.

In the GRI-Mech 1.1 release, the efficiency of water was 17. In the GRI-Mech 1.2 and 2.1 releases, the efficiency of water is 12. This was changed in the GRI-Mech 3.0 release to 8.

COMMENTS:

Served as an optimization variable in GRI-Mech 1.1, 1.2, and 2.1 releases. As a result of optimization round 1.1, the preexponential factor was increase by 1.41. However, in subsequent optimization rounds, 1.2 and 2.1, the rate coefficient was returned to the original value. Served as a variable in the GRI-Mech 3.0 release and was changed by a factor of 0.67.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   (mol/cm3)
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     300        21.1        15.7    2.05E+03    3.19E+14    6.44E-12
     500        22.8        16.3    1.11E+08    6.51E+14    1.70E-07
    1000        24.2        17.3    2.87E+11    7.33E+14    3.91E-04
    1500        24.7        17.9    3.32E+12    6.67E+14    4.97E-03
    2000        24.8        18.2    1.03E+13    6.13E+14    1.69E-02
    2500        24.9        18.4    1.95E+13    5.75E+14    3.39E-02
    3000        25.0        18.5    2.87E+13    5.48E+14    5.25E-02
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