HO2 + CH3 -> O2 + CH4

SOURCE:

Reid, A.B., Robinson, C., and Smith, D.B. (1984) 20th Symposium (International) on Combustion, p. 1833.

COMMENTS:

Served as an optimization variable in GRI-Mech 1.1, 1.2, 2.1 and 3.0 releases. The rate coefficient was not changed.

______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
______________________________________________________________________

     300        -7.6       -55.9    1.00E+12    7.93E-28    1.26E+39
     500        -8.6       -56.3    1.00E+12    1.77E-11    5.64E+22
    1000        -9.0       -56.6    1.00E+12    3.99E+01    2.50E+10
    1500        -8.6       -56.1    1.00E+12    5.14E+05    1.95E+06
    2000        -8.1       -55.1    1.00E+12    5.47E+07    1.83E+04
    2500        -7.5       -53.9    1.00E+12    8.52E+08    1.17E+03
    3000        -7.0       -52.5    1.00E+12    5.09E+09    1.97E+02
_____________________________________________________________________