O + CO (+M) -> CO2 (+M)

k_o = 6.02E+14 exp(-3000 cal/mol /RT) cm^6/mol^2 s

k_inf = 1.80E+10 exp(-2385 cal/mol /RT) cm^3/mol s

Lindemann Falloff

Third-body efficiencies:

N2 1.0

H2 Enhanced by 2.0

O2 Enhanced by 6.0

H2O Enhanced by 6.0

CH4 Enhanced by 2.0

CO Enhanced by 1.5

CO2 Enhanced by 3.5

C2H6 Enhanced by 3.0

AR Enhanced by 0.5

SOURCE:: Tsang, W., and Hampson, R.F. (1986) J. Phys. Chem. Ref. Data 15, 1087.; Pressure dependence was added in GRI-Mech 3.0, using k(inf) from J. Troe, 15th Symp. (Int'l.) on Combustion, 9.667 (1974).

                        PRESSURE = 0.1 atm N2
______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   (cm3/mol)
______________________________________________________________________

     300       -34.7      -127.2    1.49E+07    4.98E-83    2.99E+89
     500       -35.9      -127.7    6.87E+07    1.86E-45    3.70E+52
    1000       -36.3      -127.9    1.57E+08    1.83E-17    8.57E+24
    1500       -36.2      -127.8    1.75E+08    2.82E-08    6.21E+15
    2000       -36.0      -127.4    1.70E+08    9.14E-04    1.86E+11
    2500       -35.8      -127.0    1.58E+08    4.10E-01    3.85E+08
    3000       -35.7      -126.5    1.46E+08    2.23E+01    6.56E+06
______________________________________________________________________

                        PRESSURE = 1 atm N2
______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   (mol/cm3)
______________________________________________________________________

     300       -34.7      -127.2    9.25E+07    3.09E-82    2.99E+89
     500       -35.9      -127.7    4.98E+08    1.35E-44    3.70E+52
    1000       -36.3      -127.9    1.25E+09    1.46E-16    8.57E+24
    1500       -36.2      -127.8    1.46E+09    2.35E-07    6.21E+15
    2000       -36.0      -127.4    1.47E+09    7.90E-03    1.86E+11
    2500       -35.8      -127.0    1.40E+09    3.64E+00    3.85E+08
    3000       -35.7      -126.5    1.32E+09    2.01E+02    6.56E+06
______________________________________________________________________


                        PRESSURE = 10 atm N2
______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   (mol/cm3)
______________________________________________________________________

     300       -34.7      -127.2    1.93E+08    6.45E-82    2.99E+89
     500       -35.9      -127.7    1.33E+09    3.59E-44    3.70E+52
    1000       -36.3      -127.9    4.06E+09    4.74E-16    8.57E+24
    1500       -36.2      -127.8    5.57E+09    8.97E-07    6.21E+15
    2000       -36.0      -127.4    6.29E+09    3.38E-02    1.86E+11
    2500       -35.8      -127.0    6.56E+09    1.70E+01    3.85E+08
    3000       -35.7      -126.5    6.66E+09    1.02E+03    6.56E+06
______________________________________________________________________

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