OH + CH3 -> H2 + CH2O

SOURCE:

The parameters represent the results of a 5-channel RRKM calculation on the CH3OH system.

COMMENTS:

This reaction channel was added to the mechanism in version 3.0. The likely product is HCOH, which rapidly isomerizes to CH2O.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300        -6.8       -70.5    2.62E+12    0.00E+00    
     500        -7.1       -70.6    1.05E+12    0.00E+00    
    1000        -7.0       -70.5    6.12E+11    0.00E+00    
    1500        -6.7       -70.2    5.58E+11    0.00E+00    
    2000        -6.6       -69.9    5.55E+11    0.00E+00    
    2500        -6.5       -69.7    5.69E+11    0.00E+00    
    3000        -6.5       -69.6    5.88E+11    0.00E+00    
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