Herron, J.T., and Penzhorn, R.D. (1969)
Mass Spectrometric Study of the Reactions of Atomic Oxygen with
Ethylene and Formaldehyde
J. Phys. Chem. 1969, 73, 191.
Abstract
A mass spectrometric study has been made of the reactions of atomic oxygen with
ethylene and formaldehyde. The formation of in the ethylene reaction is shown to
be independent of the presence of molecular oxygen and is attributed to a
reaction between atomic oxygen and methyl radicals. The rate constant for the
reaction of atomic oxygen with formaldehyde is 9.0E+10 cm3/mol s at 300 K.
REACTION RATE COEFFICIENTS SUGGESTED IN THIS WORK:
GRI-Mech
Number
('-' sign
means
reverse) |
Reaction |
Rate Coefficient
A T^n exp(-E/RT) |
Temperature
Range
(K) |
A
(mol,cm3,s) |
n
(T in K) |
E
(cal/mol) |
| 15 |
O + CH2O -> OH + HCO |
9.0E+10 |
|
|
300 |