Shibuya, K., Ebata, T., Obi, K., and Tanaka, I. (1977)
Rate Constant Measurements for the Reactions of HCO with NO and
O2 in the Gas Phase
J. Phys. Chem. 1977, 81, 2292.
Abstract
The behavior of the HCO radical produced by the flash photolysis of gaseous
acetaldehyde has been studied with and without so-called radical scavengers at
room temperature. The analysis of the results gives rate constants of
(8.5±1.0)E-12 and (5.6±0.9)E-12 cm3/mol s for the reactions of the HCO
radical with NO and O2, respectively.
REACTION RATE COEFFICIENTS SUGGESTED IN THIS WORK:
GRI-Mech
Number
('-' sign
means
reverse) |
Reaction |
Rate Coefficient
A T^n exp(-E/RT) |
Temperature
Range
(K) |
A
(mol,cm3,s) |
n
(T in K) |
E
(cal/mol) |
| A |
HCO + O2 -> products |
3.37E+12 |
|
|
298 |
| B |
HCO + NO -> HNO + CO |
5.12E+12 |
|
|
298 |