Westenberg, A.A., and deHaas, N. (1972)
Measurement of the Rate Constant for H + H2CO -> H2 + HCO at
297-652 K
J. Phys. Chem. 1972, 76, 2213.
Abstract
Absolute measurements of the rate constant for the reaction (58) over the temperature range
297-652 K are reported. A fast-flow reactor with esr detection for H atom decay
was used. The Arrhenius expression obtained for k(58) is shown below. Comparisons
with other data are made.
REACTION RATE COEFFICIENTS SUGGESTED IN THIS WORK:
GRI-Mech
Number
('-' sign
means
reverse) |
Reaction |
Rate Coefficient
A T^n exp(-E/RT) |
Temperature
Range
(K) |
A
(mol,cm3,s) |
n
(T in K) |
E
(cal/mol) |
| 58 |
H + CH2O -> HCO + H2 |
1.35E+13 |
|
3760 |
297-652 |