CH2(S) + NO -> OH + HCN
k = 2.90E+14 T^(-0.69) exp(-760 cal/mol /RT) cm3/mol s
- SOURCE:
- The rate coefficient for the singlet reaction was assumed
identical to the triplet since the reaction is exothermic.
Dean, A.M., and Bozzelli, J.W. (1996)
in Combustion Chemistry II, Springer-Verlag, New York.
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Temp delta-S delta-H kf kr Keq
(K) (cal/mol K) (kcal/mol) ----(mol,cm3,s)-----
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300 -3.4 -82.9 1.58E+12 3.70E-48 4.28E+59
500 -3.0 -82.7 1.85E+12 5.90E-24 3.14E+35
1000 -2.4 -82.3 1.68E+12 5.81E-06 2.90E+17
1500 -2.1 -82.0 1.45E+12 4.81E+00 3.00E+11
2000 -1.9 -81.6 1.26E+12 4.02E+03 3.15E+08
2500 -1.7 -81.1 1.13E+12 2.15E+05 5.23E+06
3000 -1.5 -80.6 1.02E+12 2.93E+06 3.47E+05
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