H + HCN + M -> H2CN + M


k = 1.40E+26 T^(-3.4) exp(-1900 cal/mol /RT) cm3/mol s

Third-body efficiencies:

N2 1.0 H2 Enhanced by 2.0 H2O Enhanced by 6.0 CH4 Enhanced by 2.0 CO Enhanced by 1.5 CO2 Enhanced by 2.0 C2H6 Enhanced by 3.0 AR Enhanced by 0.7


SOURCE:
Calculated using theoretical approch of Troe, J. (1977) J. Chem. Phys. 66, 4745 and Patrick, R., and Golden, D.M. (1983) Int. J. Chem. Kinet. 15, 1189.
The reverse decomposition rates agree with the recommendation of Dean, A.M., and Bozzelli, J.W. (1996) in Combustion Chemistry II, Springer-Verlag, New York.

______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----    (cm3/mol)
______________________________________________________________________

     300       -22.1       -25.3    2.19E+16    2.35E-02    9.29E+17
     500       -24.1       -26.1    1.38E+16    2.58E+05    5.34E+10
    1000       -25.9       -27.2    3.40E+15    2.07E+10    1.64E+05
    1500       -26.4       -27.9    1.18E+15    4.83E+11    2.43E+03
    2000       -26.6       -28.3    5.19E+14    1.68E+12    3.08E+02
    2500       -26.7       -28.6    2.67E+14    2.90E+12    9.21E+01
    3000       -26.8       -28.8    1.53E+14    3.63E+12    4.22E+01
______________________________________________________________________

[ Rate coefficient format | Chemkin file | Thermo data | Main menu ]