HNCO + M -> NH + CO + M


k = 1.18E+16 exp(-84720 cal/mol /RT) cm3/mol s

Third-body efficiencies:

N2 1.0 H2 Enhanced by 2.0 H2O Enhanced by 6.0 CH4 Enhanced by 2.0 CO Enhanced by 1.5 CO2 Enhanced by 2.0 C2H6 Enhanced by 3.0 AR Enhanced by 0.7


SOURCE:
Wu, C.H., Wang, H.T., Lin, M.C., and Fifer, R.A. (1990) J. Phys. Chem. 94, 3344.

______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----    (mol/cm3)
______________________________________________________________________

     300        33.0        87.1    2.26E-46    9.71E+14    2.33E-61
     500        34.0        87.5    1.10E-21    2.88E+14    3.82E-36
    1000        33.8        87.3    3.60E-03    1.44E+14    2.51E-17
    1500        33.2        86.6    5.35E+03    1.47E+14    3.64E-11
    2000        32.8        85.8    6.52E+06    1.73E+14    3.77E-08
    2500        32.5        85.1    4.63E+08    2.09E+14    2.22E-06
    3000        32.2        84.4    7.95E+09    2.50E+14    3.18E-05
______________________________________________________________________

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