NCO + NO -> N2O + CO


k = 2.85E+17 T^(-1.52) exp(-740 cal/mol /RT) cm3/mol s


SOURCE:
Overall rate from Mertens, J.D., Dean, A.J., Hanson, R.K., and Bowman, C.T. (1992) 24th Symposium (International) on Combustion, p.  701.
Branching ratio from Lin., M.C., He, Y., and Melius, C.F. (1993) J. Phys. Chem. 97, 9124

COMMENTS:
Served as an optimization variable in GRI-Mech 2.1 release. The preexponential factor was increased by a factor of 1.5.


______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
______________________________________________________________________

     300        -6.1       -60.2    4.80E+20    1.37E-22    3.50E+42
     500        -6.3       -60.3    1.71E+21    1.78E-04    9.62E+24
    1000        -6.6       -60.5    7.13E+21    1.18E+10    6.07E+11
    1500        -6.7       -60.6    1.50E+22    6.38E+14    2.34E+07
    2000        -6.7       -60.6    2.46E+22    1.70E+17    1.45E+05
    2500        -6.7       -60.6    3.59E+22    5.23E+18    6.86E+03
    3000        -6.6       -60.4    4.85E+22    5.39E+19    9.01E+02
______________________________________________________________________

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