CH3 + HCO -> CH4 + CO

SOURCE:

Mulenko, S.A. (1987) Rev. Roum. Phys. 32, 173.

COMMENTS:

Served as an optimization variable in GRI-Mech 1.1, 1.2, and 2.1 releases. As a result of optimization round 1.1, the rate coefficient was decrease by a factor of 0.44. However, after that, in optimization rounds 1.2 and 2.1, the rate coefficient was returned to the original value reported above.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300        -8.2       -89.4    2.65E+13    1.24E-50    2.14E+63
     500        -9.2       -89.8    2.65E+13    1.55E-24    1.71E+37
    1000        -9.9       -90.2    2.65E+13    7.35E-05    3.61E+17
    1500        -9.7       -89.9    2.65E+13    2.71E+02    9.77E+10
    2000        -9.2       -89.1    2.65E+13    4.98E+05    5.32E+07
    2500        -8.7       -88.0    2.65E+13    4.31E+07    6.15E+05
    3000        -8.2       -86.5    2.65E+13    8.07E+08    3.28E+04
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