CH2(S) + O2 -> CO + H2O

SOURCE:

The rate coefficient of Langford et al. (1983) using the branching ratio suggested by Shaub et al. (1981).

REFERENCES:

Langford et al. (1983)

Langford, A.O., Petek, H., and Moore, C.B. (1983) J. Chem. Phys. 78, 6650.

Shaub et al. (1981)

Shaub, W.M., Hsu, D.S.Y., Burks, T.L., and Lin, M.C. (1981) 18th Symposium (International) on Combustion, p. 811.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----    
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     300        -1.9      -187.0    1.20E+13    1.96-123    6.11+135
     500        -2.0      -187.0    1.20E+13    6.00E-69    2.00E+81
    1000        -2.7      -187.5    1.20E+13    4.84E-28    2.48E+40
    1500        -3.1      -188.0    1.20E+13    2.29E-14    5.24E+26
    2000        -3.3      -188.4    1.20E+13    1.64E-07    7.31E+19
    2500        -3.4      -188.7    1.20E+13    2.16E-03    5.55E+15
    3000        -3.5      -188.9    1.20E+13    1.22E+00    9.87E+12
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