CH3 + H2O2 -> HO2 + CH4

SOURCE:

TST fit to reverse reaction rate data of Baldwin, R.R., Jones, P.N., and Walker, R.W. (1988) J. Chem. Soc. Farad. Trans. 2 84, 199.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300        -3.1       -17.5    5.42E+06    4.95E-06    1.10E+12
     500        -4.4       -18.0    6.19E+08    7.98E+01    7.76E+06
    1000        -5.2       -18.5    4.65E+10    5.80E+07    8.01E+02
    1500        -5.0       -18.2    3.02E+11    8.23E+09    3.66E+01
    2000        -4.5       -17.3    9.48E+11    1.15E+11    8.22E+00
    2500        -3.9       -16.1    2.13E+12    6.04E+11    3.53E+00
    3000        -3.3       -14.5    3.98E+12    1.89E+12    2.11E+00
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