CH3 + O2 -> OH + CH2O

SOURCE:

Fraatz, W., and Zellner, R. (1992) unpublished results.

COMMENTS:

Served as an optimization variable in GRI-Mech 1.1, 1.2, and 2.1 releases. The rate coefficient was not changed.

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    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
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     300          .8       -51.7    1.11E+04    1.73E-34    6.40E+37
     500          .4       -51.8    4.45E+06    8.18E-17    5.45E+22
    1000          .1       -52.0    4.00E+08    1.62E-03    2.47E+11
    1500         0.0       -52.1    1.79E+09    4.52E+01    3.97E+07
    2000         0.0       -52.2    3.80E+09    7.60E+03    5.00E+05
    2500         -.1       -52.3    5.95E+09    1.65E+05    3.60E+04
    3000         -.1       -52.5    8.04E+09    1.29E+06    6.21E+03
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