O + C2H5 -> CH3 + CH2O

SOURCE:

Rate coefficient is from Slagle et al. (1988).

COMMENTS:

These products are estimated by Tsang and Hampson (1986) to account for 17% of the reaction. Their main product channel, producing CH3CHO and H, was not adopted in order to avoid accounting for CH3CHO reactions in the mechanism.

REFERENCES:

Slagle et al. (1988)

Slagle, I.R., Sarzynski, D., Gutman, D., Miller, J.A., and Melius, C.F. (1988) J. Chem. Soc. Farad. Trans. 84, 491.

Tsang and Hampson (1986)

Tsang, W., and Hampson, R.F. (1986) J. Phys. Chem. Ref. Data 15, 1087.

______________________________________________________________________
    Temp      delta-S     delta-H      kf          kr         Keq
     (K)    (cal/mol K)  (kcal/mol) ----(mol,cm3,s)-----   
______________________________________________________________________

     300         1.1       -78.8    1.32E+14    3.23E-44    4.09E+57
     500          .9       -78.8    1.32E+14    2.88E-21    4.58E+34
    1000         -.1       -79.6    1.32E+14    5.58E-04    2.36E+17
    1500         -.9       -80.6    1.32E+14    3.78E+02    3.50E+11
    2000        -1.5       -81.6    1.32E+14    3.38E+05    3.91E+08
    2500        -1.9       -82.6    1.32E+14    2.10E+07    6.29E+06
    3000        -2.3       -83.6    1.32E+14    3.40E+08    3.88E+05
______________________________________________________________________