OH + H2O2 -> HO2 + H2O
k = 1.75E+12 exp(-320 cal/mol /RT)
+ 5.80E+14 exp(-9560 cal/mol /RT) cm3/mol s
- SOURCE:
- The reaction is entered twice to provide a dual-exponential fit
to the following data:
- DeMore, W.B., Sander, S.P., Golden, D.M., Hampson, R.F., Kurylo,
M.J., Howard, C.J., Ravishankara, A.R., Kolb, C.E., and Molina, M.J. (1992)
Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling
Evaluation 10, JPL Publication 92-20.
- Hippler, H., and Troe, J. (1992)
Chem. Phys. Lett. 192, 333.
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Temp delta-S delta-H kf kr Keq
(K) (cal/mol K) (kcal/mol) ----(mol,cm3,s)-----
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300 -.1 -31.7 1.02E+12 8.23E-12 1.24E+23
500 -.6 -31.9 1.31E+12 1.96E-02 6.68E+13
1000 -1.4 -32.5 6.21E+12 9.92E+05 6.26E+06
1500 -1.8 -32.9 2.51E+13 9.64E+08 2.60E+04
2000 -1.9 -33.2 5.39E+13 3.33E+10 1.62E+03
2500 -1.9 -33.2 8.63E+13 2.83E+11 3.05E+02
3000 -1.9 -33.1 1.19E+14 1.19E+12 1.00E+02
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