| Description of target | Sensitivity diagram | Prediction of GRI-Mech 2.11 |

DESCRIPTION OF THE TARGET

Target NF12/13: Ratio of CN peak concentrations for NO and N2O doping in a laminar premixed flame

Mixtures: CH4-O2-NO-Ar (19.01%-38%-1.2%-41.79%);
CH4-O2-N2O-Ar (19.01%-38%-1.2%-41.79%)
phi = 1.0; P = 10 torr; flow rate = 1.8e-3 gm/cm^2 s

Reference: Williams, B.A. and Fleming, J.W., 'Comparative Species Concentrations in CH4/O2/Ar Flames Doped with N2O, NO and NO2,' Combustion and Flame 98:93 (1994).

TARGET VALUES
Experimental
[CN](NO=1.2%)
/[CN](N2O=1.2%)
Initial (unoptimized)
mechanism
GRI-Mech 2.11
2.9 4.4 3.2


SENSITIVITY DIAGRAM

The sensitivity spectrum shown below was computed with a reaction mechanism composed of GRI-Mech 1.2 and an evaluated 'literature' (i.e., non-optimized) set of 99 reactions of nitrogen-containing species


|NF1| NF2| NF3| NFR1| NFR2| NFR3| NF6| NF7| NF8| NF9| NF10| NF11| NF12|